I began by using the dodge tool to whiten the eye's white area to make it look brighter. I then used the burn tool to enhance the dark zones within the iris.
I then created a quick mask to use over the part of the eye I wanted to make blue violet. I used the brush tool to cover the eye before applying the color. I ran into problems while using the quick mask and the brush, but I figured out how to use it better through trial and error.
I got rid of the excess color and then I used the burn tool again to enhance the dark zones in the iris. This is the finished product.
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